PCOD1000015
[Ca₄Al₇F₃₃]^4-, a = 10.860 A
Known with Na atoms in the holes, as Na₄Ca₄Al₇F₃₃

PCOD1000017
AlF₃, a = 9.668 A
known with some OH^- and water in the holes : pyrochlore

PCOD1010005
[Ca₃Al₄F₂₁]^3-, a = 9.009 A
UNKNOWN - Could be stuffed by Na and give the hypothetical Na₃Ca₃Al₄F₂₁ ?? or stuffed by Li ?? or ??

PCOD1000014
AlF₃, a = 10.216 A, c = 7.241 A
Known as t-AlF₃